DEVELOPMENT OF KINETIC MODELS FOR THE COMPLEX CHEMICAL REACTIONS BY THE NETWORK OPERATOR
A new method for the identification of mathematical models of complex chemical reactions is presented. The authors note that the principle of mass action in chemical kinetics doesn´t always describe the complex chemical reactions adequately, and for such cases suggest to use the network operator method. The network operator method is used to present a mathematical model in a matrix form. To find the optimal model authors use multicriterial variational genetic algorithm that searches on a set of small variations of given possible solutions. In the computational experiment it is considered a chemical reaction of olefine hydroalumination by organoaluminum compounds in the presence of a catalyst. Results of computational experiments show an adequate description of complex chemical reactions and confirm the effectiveness of the network operator method for deriving kinetic equations.