Structure of Organic and Organoelemental Compounds. Part 1
The structure of seven organic and organoelemental compounds was determined by X-ray structural analysis (XRD). XRD analysis of compounds was performed on an automatic four-circle diffractometer D8 Quest Bruker (Мо К<sub>α</sub> , λ = 0.71073 Å, 293 К. [ p -Tol<sub>4</sub>Sb]{[F<sub>3</sub>CC(O)CHC(O)CF<sub>3</sub>]<sub>2</sub>Li} (1) P -1, a = 8.662(15), b = 11.964(18), c = 20.94(5) Å, a = 65.71(9), β = 95.20(7), g = 102.74(5) deg., V = 2092(7) Å<sup>3</sup>, Z = 2. [Ph<sub>4</sub>Sb][PhC(O)CHC(O)Ph] (2), P 21/n, a = 11.335(5) Å, b = 14.975(7) Å, c = 19.017(9) Å, β = 101.671(16) deg., V = 3161(3) Å<sup>3</sup>, Z = 4. HOC(O)C<sub>6</sub>H<sub>4</sub>(NO<sub>2</sub>-2) (3), P -1, a = 5.023(4), b = 7.556(10), c = 10.611(9) Å, a = 69 . 16(4), β = 86.07(4) , g = 71.10(6) deg., V = 355.6(6) Å<sup>3</sup>, Z = 2. [Ph<sub>3</sub>PCH<sub>2</sub>Ph]Br·DMSO (4), P -1, a = 10.09(3), b = 10.85(2), c = 24.80(5) Å, a = 80.42(7), β = 80.26(9) , g = 77.36(12) deg., V = 2588(10) Å<sup>3</sup>, Z = 2. [(2-MeO)(Br-5)C<sub>6</sub>H<sub>3</sub>]<sub>3</sub>Sb×0.5PhH (5), P 21/n, a = 9.082(7), b = 21.248(12), c = 13.802(12) Å, β = 106.09(4) deg., V = 2559(3) Å<sup>3</sup>, Z = 4. Ph<sub>4</sub>SbNO<sub>3</sub>·PhH (6), Cc , a = 10.573(7), b = 17.484(7), c = 14.647(4) Å, β = 92 . 934(15) deg., V = 2704.1(16) Å<sup>3</sup>, Z = 4. [(2-MeO)(Cl-5)C<sub>6</sub>H<sub>3</sub>]<sub>3</sub>Bi · ½ PhH (7), P 21/n, a = 8.920(5) Å, b = 21.362(7) Å, c = 13.649(5) Å, β = 107.33(2) deg., V = 2482,8(17) Å<sup>3</sup>, Z = 4.