AN ANALYSIS OF THE GENERAL KINETIC SCHEME OF CATALYSIS IN THE REACTIONS OF ACTIVATED BENZENE DERIVATIVES WITH PRIMARY AMINES BY ORGANIC BASES IN NON-POLAR MEDIA
From the analysis of the general kinetic scheme for catalysis with only organic base, it is shown that the observed rate constant can have both the first and second order with respect the configuration of the organic base. In the case when the formation of σ-complex it the slowest stage, the catalysis process through an associative mechanism only, when in the case of a limiting destruction - only through a stage mechanism.